| John C. Westall |
Analytical Chemistry |
Research Interests
Dr. Westall's research is focused on the
application of surface and solution chemistry to problems in
environmental chemistry, electrochemistry, and analytical chemistry.
Current research topics include: (i) interactions of metal ions with
heterogeneous environmental complexants, such as humic substances and
surfaces of soil particles, and development of models for these complex
interactions; (ii) electrochemical processes in the environment,
including corrosion and redox transformations of inorganic and organic
pollutants; (iii) the processes that control the distribution of
hydrophobic, ionogenic, and ionic organic compounds between water and
environmental sorbents; (iv) electric double layer phenomena associated
with environmental surfaces; (v) mathematical methods for the
determination of equilibrium constants from experimental data; (vi) the
application of multicomponent chemical equilibrium models to
biogeochemical problems.
|
|
Representative Publications
- Role of
Surface Alteration in Determining the Mobility of U(VI) in the Presence of Citrate:
Implications for Extraction of U(VI) from Soils, Environ. Sci. Technol.,
2004, 38, 3752-3759.
- Kinetics of
Reduction of Nitrobenzene and Carbon Tetrachloride at an Iron-Oxide Coated Gold Electrode,
Environ. Sci. Technol., 2003, 37, 2356-2362.
- Mass Transport
Effects on the Kinetics of Nitrobenzene Reduction by Iron Metal, Environ. Sci.
Technol., 2001, 35, 2804-2811.
- Evaluation of Liposome-Water Partitioning of Organic Acids and Bases:
1. Development of a Sorption
Model,
2. Comparison of
Experimental Determination Methods, Environ. Sci. Technol., 2000,
34, 3954-3968.
- Sorption of
Linear Alkylbenzenesulfonates on Sediment Materials, Environ. Sci. Technol.,
1999, 33, 3110-3118.
- Sequestration
of Hydrophobic Organic Contaminants by Geosorbents - Critical Review, Environ. Sci.
Technol., 1997, 31, 3341
- Models for Association of Metal Ions with Heterogeneous Environmental
Sorbents: I. Complexation of Co(II) by Leonardite Humic Acid as a Function of pH and
NaClO4 Concentration, Environ. Sci. Technol., 1995, 29,
951.
- Use of Cationic Surfactants to Modify Soil Surfaces To Promote
Sorption and Retard Migration of Hydrophobic Organic Compounds, Environ. Sci.
Technol., 1994, 28, 231.
- The Study of Soil Chemistry Through Quasi-Steady-State Models: II.
Acidity of Soil Solution, Geochim. Cosmochim. Acta, 1990, 54, 2363.
|